20/12/2021 - 13:00 - 12:00
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2021-12-20 12:00:00
2021-12-20 13:00:00
קולוקוויום מחלקתי 20.12.2021
מפגש הקולוקויום יתקיים ביום שני 20/12/2021 בשעה 12:00 בחדר הסמינרים המחלקתי (112).
עקב מזג אוויר סוער הצפוי מחר , נאפשר באופן חד פעמי כניסה להרצאתו של ד"ר יגאל לוין מחר בשעה 12:00 דרך זום.
זה הקישור להרצאה מחר:
https://us02web.zoom.us/j/6155611589
The Department of Chemistry Weekly Seminar will take place on Monday 20/12/21, 12:00pm.
Due to the expected stormy weather, there is one-time option to entry Dr. Yigal Levin's lecture via Zoom.
Click here to join the lecture
Defect Hunting in Halide Perovskites
Dr. Igal Levine (Division of Solar Energy Research Helmholtz-Zentrum Berlin)
Non-radiative recombination of electronic charge carriers in a semiconductor via defect states can strongly limit the performance of optoelectronic device such as solar cells. Therefore, detecting and characterizing deep defect states in the band gap of semiconductors is important for identifying limiting factors in electronic devices, and constitutes a necessary step for further device development, as well as presenting often a technical and scientific challenge. Direct detection of defects in halide perovskites (HaPs) by standard methods utilizing optical excitation is quite challenging, due to the relatively low density of defects present in these family of materials ( 1015 cm-3). In this talk I will show how the use of a combination of high-sensitivity contactless techniques such as modulated surface photovoltage (SPV) and low-energy photoelectron spectroscopy, can directly probe the energetic location of defects in the bulk of Br-based wide-bandgap (Eg > 2eV) HaPs, and explain the significant open-circuit voltage losses in solar cells based on Br-based HaPs. In addition, I will show how time-resolved SPV and time-resolved Photoluminescence provide complementary information on charge transfer kinetics and trapping/de-trapping mechanisms at different charge selective layers / HaP interfaces. A minimalistic kinetic model based only on rate equations has been developed for the simulation of SPV transients, allowing quantification of the density of interface traps and the hole transfer rate constants for different charge selective layers. Finally, I will show how these extracted quantities correlated very well with the resulting performance of the corresponding solar cells, and explain the recent world record photoconversion efficiency of perovskite / silicon tandem solar cells.
Invitation (PDF)
חדר הסמינרים 211/112, Zoom
Department of Chemistry
chemistry.office@biu.ac.il
Asia/Jerusalem
public
מיקום
חדר הסמינרים 211/112, Zoom
מפגש הקולוקויום יתקיים ביום שני 20/12/2021 בשעה 12:00 בחדר הסמינרים המחלקתי (112).
עקב מזג אוויר סוער הצפוי מחר , נאפשר באופן חד פעמי כניסה להרצאתו של ד"ר יגאל לוין מחר בשעה 12:00 דרך זום.
זה הקישור להרצאה מחר:
https://us02web.zoom.us/j/6155611589
The Department of Chemistry Weekly Seminar will take place on Monday 20/12/21, 12:00pm.
Due to the expected stormy weather, there is one-time option to entry Dr. Yigal Levin's lecture via Zoom.
Click here to join the lecture
Defect Hunting in Halide Perovskites
Dr. Igal Levine (Division of Solar Energy Research Helmholtz-Zentrum Berlin)
Non-radiative recombination of electronic charge carriers in a semiconductor via defect states can strongly limit the performance of optoelectronic device such as solar cells. Therefore, detecting and characterizing deep defect states in the band gap of semiconductors is important for identifying limiting factors in electronic devices, and constitutes a necessary step for further device development, as well as presenting often a technical and scientific challenge. Direct detection of defects in halide perovskites (HaPs) by standard methods utilizing optical excitation is quite challenging, due to the relatively low density of defects present in these family of materials ( 1015 cm-3). In this talk I will show how the use of a combination of high-sensitivity contactless techniques such as modulated surface photovoltage (SPV) and low-energy photoelectron spectroscopy, can directly probe the energetic location of defects in the bulk of Br-based wide-bandgap (Eg > 2eV) HaPs, and explain the significant open-circuit voltage losses in solar cells based on Br-based HaPs. In addition, I will show how time-resolved SPV and time-resolved Photoluminescence provide complementary information on charge transfer kinetics and trapping/de-trapping mechanisms at different charge selective layers / HaP interfaces. A minimalistic kinetic model based only on rate equations has been developed for the simulation of SPV transients, allowing quantification of the density of interface traps and the hole transfer rate constants for different charge selective layers. Finally, I will show how these extracted quantities correlated very well with the resulting performance of the corresponding solar cells, and explain the recent world record photoconversion efficiency of perovskite / silicon tandem solar cells.
Invitation (PDF)
